Issue 28, 2015

Multilayered paper-like electrodes composed of alternating stacked mesoporous Mo2N nanobelts and reduced graphene oxide for flexible all-solid-state supercapacitors

Abstract

Flexible all-solid-state supercapacitors (SCs) have great potential in flexible and wearable electronics due to their safety, flexibility, high power density, and portability. The energy storage properties of SCs are determined mainly by their composition and conductivity as well as the configuration of the integrated electrode material. Herein, a freestanding multilayered film electrode consisting of alternating stacked mesoporous Mo2N nanobelts and rGO nanosheets (MMNNBs/rGO) is described. The electrode has a high mass loading of 95.6 wt% of the Mo2N active material and boasts high areal capacitances of 142 and 98 mF cm−2 at current densities of 1 and 150 mA cm−2, respectively. All-solid-state SCs fabricated by sandwiching two thin and flexible freestanding MMNNBs/rGO hybrid electrodes with a poly (vinyl alcohol) (PVA)/H3PO4/silicotungstic acid (SiWA) gel electrolyte show a high volumetric capacitance of 15.4 F cm−3 as well as energy and power densities of 1.05 mW h cm−3 and 0.035 W cm−3 at a current density of 0.1 A cm−3 based on the volume of the entire cell. After 4000 charging–discharging cycles, the flexible SC retains 85.7% initial capacitance, thus exhibiting good cycling stability. This study provides a versatile method for the fabrication of flexible and high-performance ceramic-based nanohybrid films for SCs, and has immense potential in flexible and wearable electronics.

Graphical abstract: Multilayered paper-like electrodes composed of alternating stacked mesoporous Mo2N nanobelts and reduced graphene oxide for flexible all-solid-state supercapacitors

Supplementary files

Article information

Article type
Paper
Submitted
19 Apr 2015
Accepted
31 May 2015
First published
01 Jun 2015

J. Mater. Chem. A, 2015,3, 14617-14624

Author version available

Multilayered paper-like electrodes composed of alternating stacked mesoporous Mo2N nanobelts and reduced graphene oxide for flexible all-solid-state supercapacitors

G. Ma, Z. Wang, B. Gao, T. Ding, Q. Zhong, X. Peng, J. Su, B. Hu, L. Yuan, P. K. Chu, J. Zhou and K. Huo, J. Mater. Chem. A, 2015, 3, 14617 DOI: 10.1039/C5TA02851E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements