Issue 45, 2016

Synthesis of –C[double bond, length as m-dash]N– linked covalent organic frameworks via the direct condensation of acetals and amines

Abstract

We demonstrate herein a facile approach for constructing –C[double bond, length as m-dash]N– linked COFs from acetals. Three new COFs (imine-linked LZU-20, hydrazone-linked LZU-21, and azine-linked LZU-22) were synthesized by the direct condensation of dimethyl acetals and amines. All the synthesized COFs are highly crystalline and exhibit good thermal stability.

Graphical abstract: Synthesis of –C [[double bond, length as m-dash]] N– linked covalent organic frameworks via the direct condensation of acetals and amines

Supplementary files

Article information

Article type
Communication
Submitted
30 Jan 2016
Accepted
12 Apr 2016
First published
19 Apr 2016

Chem. Commun., 2016,52, 7217-7220

Synthesis of –C[double bond, length as m-dash]N– linked covalent organic frameworks via the direct condensation of acetals and amines

Z. Li, S. Ding, H. Xue, W. Cao and W. Wang, Chem. Commun., 2016, 52, 7217 DOI: 10.1039/C6CC00947F

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