Issue 40, 2016

Oxygen insertion into boroles as a route to 1,2-oxaborines

Abstract

The synthesis of 1,2-oxaborines is accomplished via the reaction of pentaarylboroles with N-methylmorpholine-N-oxide via a 1,1-insertion reaction. The aromatic nature of 1,2-oxaborines was evaluated by computing nuclear independent chemical shift (NICS) values. Collectively, the experimental and computational studies indicate the unsaturated central BOC4 ring has appreciable aromatic character.

Graphical abstract: Oxygen insertion into boroles as a route to 1,2-oxaborines

Supplementary files

Article information

Article type
Communication
Submitted
07 Mar 2016
Accepted
26 Mar 2016
First published
29 Mar 2016

Chem. Commun., 2016,52, 6658-6661

Oxygen insertion into boroles as a route to 1,2-oxaborines

S. Yruegas, D. C. Patterson and C. D. Martin, Chem. Commun., 2016, 52, 6658 DOI: 10.1039/C6CC02040B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements