Issue 38, 2016

Ba4Ru3O10.2(OH)1.8: a new member of the layered hexagonal perovskite family crystallised from water

Abstract

A new barium ruthenium oxyhydroxide Ba4Ru3O10.2(OH)1.8 crystallises under hydrothermal conditions at 200 °C: powder neutron diffraction data show it adopts an 8H hexagonal perovskite structure with a new stacking sequence, while high resolution electron microscopy reveals regions of ordered layers of vacant Ru sites, and magnetometry shows antiferromagnetism with TN = 200(5) K.

Graphical abstract: Ba4Ru3O10.2(OH)1.8: a new member of the layered hexagonal perovskite family crystallised from water

Supplementary files

Article information

Article type
Communication
Submitted
10 Mar 2016
Accepted
07 Apr 2016
First published
07 Apr 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 6375-6378

Ba4Ru3O10.2(OH)1.8: a new member of the layered hexagonal perovskite family crystallised from water

C. I. Hiley, M. R. Lees, D. L. Hammond, R. J. Kashtiban, J. Sloan, R. I. Smith and R. I. Walton, Chem. Commun., 2016, 52, 6375 DOI: 10.1039/C6CC02121B

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