Issue 45, 2016
From the journal:

Chemical Communications

Oxidative nucleophilic aromatic amination of nitrobenzenes†

V. V. Khutorianskyi,a   M. Sonawane,a   M. Pošta,a   B. Klepetářováa  and  P. Beier*a  

* Corresponding authors

a Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 166 10 Prague, Czech Republic
E-mail: beier@uochb.cas.cz

Abstract

Nitrobenzenes substituted with electron-acceptor groups such as halogen, nitro, trifluoromethyl, pentafluorosulfanyl, or cyano underwent oxidative nucleophilic substitution with lithium salts of arylamines to afford N-aryl-2-nitroanilines.

Graphical abstract: Oxidative nucleophilic aromatic amination of nitrobenzenes

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Article information

DOI
https://doi.org/10.1039/C6CC02235A
Article type
Communication
Submitted
14 Mar 2016
Accepted
26 Apr 2016
First published
06 May 2016

Chem. Commun., 2016,52, 7237-7240

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Oxidative nucleophilic aromatic amination of nitrobenzenes

V. V. Khutorianskyi, M. Sonawane, M. Pošta, B. Klepetářová and P. Beier, Chem. Commun., 2016, 52, 7237 DOI: 10.1039/C6CC02235A

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