NiII tetrahydronorcorroles: antiaromatic porphyrinoids with saturated pyrrole units

Ryo Nozawa; Keitaro Yamamoto; Ichiro Hisaki; Ji-Young Shin; Hiroshi Shinokubo

doi:10.1039/C6CC02918C

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Ni^II tetrahydronorcorroles: antiaromatic porphyrinoids with saturated pyrrole units†

Ryo Nozawa,^a Keitaro Yamamoto,^a Ichiro Hisaki,^b Ji-Young Shin^a and Hiroshi Shinokubo*^a

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* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, Japan
E-mail: hshino@apchem.nagoya-u.ac.jp

^b Department of Material and Life Science, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan

Abstract

While hydrogenated porphyrins are abundant in natural and synthetic compounds, antiaromatic hydrogenated porphyrinoids have not been synthesized to date. Here, we report bacteriochlorin-like Ni^II tetrahydronorcorrole complexes as the first examples of antiaromatic porphyrinoids that contain saturated pyrrole units.

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Article information

DOI: https://doi.org/10.1039/C6CC02918C
Article type: Communication
Submitted: 07 Apr 2016
Accepted: 03 May 2016
First published: 03 May 2016

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Chem. Commun., 2016,52, 7106-7109

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Ni^II tetrahydronorcorroles: antiaromatic porphyrinoids with saturated pyrrole units

R. Nozawa, K. Yamamoto, I. Hisaki, J. Shin and H. Shinokubo, Chem. Commun., 2016, 52, 7106 DOI: 10.1039/C6CC02918C

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