Issue 61, 2016
From the journal:

Chemical Communications

The coupling of hemin with persistent free radicals induces a nonradical mechanism for oxidation of pollutants†

Bin Jiang,a   Dejun Dai,a   Yuyuan Yao,*a   Tiefeng Xu,a   Renhong Li,a   Renjie Xie,a   Likun Chena  and  Wenxing Chena  

* Corresponding authors

a National Engineering Lab of Textile Fiber Materials & Processing Technology (Zhejiang), Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China

Abstract

Herein, we report that persistent free radicals (PFRs) based on MWCNTs significantly accelerate the pollutant removal rate. EPR measurement combined with the electrochemical test indicated that a nonradical mechanism was responsible for the enhancement, which is different from the previously reported radical pathway on PFRs.

Graphical abstract: The coupling of hemin with persistent free radicals induces a nonradical mechanism for oxidation of pollutants

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Article information

DOI
https://doi.org/10.1039/C6CC02973F
Article type
Communication
Submitted
09 Apr 2016
Accepted
02 Jul 2016
First published
04 Jul 2016

Chem. Commun., 2016,52, 9566-9569

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The coupling of hemin with persistent free radicals induces a nonradical mechanism for oxidation of pollutants

B. Jiang, D. Dai, Y. Yao, T. Xu, R. Li, R. Xie, L. Chen and W. Chen, Chem. Commun., 2016, 52, 9566 DOI: 10.1039/C6CC02973F

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