The substituted imidazolate-based MOF (SIM-1) easily forms a homogeneous layer at the surface of millimetric platinum-loaded alumina beads. This new core–shell SIM-1@Pt/Al2O3 catalyst shows the fine molecular sieving effect for the Pt-catalyzed hydrogenation of carbon–carbon double bonds.
S. Aguado, S. El-Jamal, F. Meunier, J. Canivet and D. Farrusseng, Chem. Commun., 2016, 52, 7161 DOI: 10.1039/C6CC03096C
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