Issue 53, 2016
From the journal:

Chemical Communications

Visible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate†

Xing-Long Yu,a   Jia-Rong Chen,*a   Dong-Zhen Chena  and  Wen-Jing Xiao*ab  

* Corresponding authors

a CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
E-mail: chenjiarong@mail.ccnu.edu.cn, wxiao@mail.ccnu.edu.cn
Fax: +86 27 67862041
Tel: +86 27 67862041

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Abstract

The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the corresponding trifluoromethylated azo compounds in generally good yields. The trifluoromethylated azo products can be easily transformed into useful heterocycles and nitrogen-containing building blocks.

Graphical abstract: Visible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate

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Article information

DOI
https://doi.org/10.1039/C6CC03335K
Article type
Communication
Submitted
21 Apr 2016
Accepted
02 Jun 2016
First published
03 Jun 2016

Chem. Commun., 2016,52, 8275-8278

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Visible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate

X. Yu, J. Chen, D. Chen and W. Xiao, Chem. Commun., 2016, 52, 8275 DOI: 10.1039/C6CC03335K

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