Issue 45, 2016

Use of an electrochemically-induced proton-coupled electron transfer reaction to control dimerization in a ureidopyrimidone 4 H-bond array

Abstract

Cyclic voltammetric and spectroelectrochemical evidence is presented showing that the H-bonded dimer formed from a ureidopyrimidone derivative containing a phenylenediamine redox couple can be reversibly broken apart at mM concentrations in CH2Cl2 by an electrochemically induced proton-coupled electron transfer reaction.

Graphical abstract: Use of an electrochemically-induced proton-coupled electron transfer reaction to control dimerization in a ureidopyrimidone 4 H-bond array

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr 2016
Accepted
04 May 2016
First published
04 May 2016

Chem. Commun., 2016,52, 7253-7256

Use of an electrochemically-induced proton-coupled electron transfer reaction to control dimerization in a ureidopyrimidone 4 H-bond array

L. A. Clare and D. K. Smith, Chem. Commun., 2016, 52, 7253 DOI: 10.1039/C6CC03365B

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