Issue 61, 2016
From the journal:

Chemical Communications

A carbon-free polyoxometalate molecular catalyst with a cobalt–arsenic core for visible light-driven water oxidation†

Wei-Chao Chen,a   Xin-Long Wang,*a   Chao Qin,a   Kui-Zhan Shao,a   Zhong-Min Su*a  and  En-Bo Wanga  

* Corresponding authors

a Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
E-mail: wangxl824@nenu.edu.cn, zmsu@nenu.edu.cn

Abstract

A carbon-free, stable, homogeneous water oxidation catalyst based on the unique hepta-nuclear cobalt–arsenic core (“fused” double-quasi-cubane) and polyoxometalate ligands, Na12[{CoII7AsIII6O9(OH)6}(A-α-SiW9O34)2]·8H2O (1), was synthesized, thoroughly characterized and employed to catalyze water oxidation under visible-light-driven conditions.

Graphical abstract: A carbon-free polyoxometalate molecular catalyst with a cobalt–arsenic core for visible light-driven water oxidation

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Article information

DOI
https://doi.org/10.1039/C6CC03763A
Article type
Communication
Submitted
05 May 2016
Accepted
21 Jun 2016
First published
21 Jun 2016

Chem. Commun., 2016,52, 9514-9517

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A carbon-free polyoxometalate molecular catalyst with a cobalt–arsenic core for visible light-driven water oxidation

W. Chen, X. Wang, C. Qin, K. Shao, Z. Su and E. Wang, Chem. Commun., 2016, 52, 9514 DOI: 10.1039/C6CC03763A

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