[Ni(OH)3W6O18(OCH2)3CCH2OH]4−: the first tris-functionalized Anderson-type heteropolytungstate

Nadiia I. Gumerova; Alexander Roller; Annette Rompel

doi:10.1039/C6CC04326G

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[Ni(OH)₃W₆O₁₈(OCH₂)₃CCH₂OH]⁴⁻: the first tris-functionalized Anderson-type heteropolytungstate†

Nadiia I. Gumerova,‡^a Alexander Roller^b and Annette Rompel

*^a

Author affiliations

* Corresponding authors

^a Universität Wien, Fakultät für Chemie, Institut für Biophysikalische Chemie, Althanstr. 14, 1090 Wien, Austria
E-mail: annette.rompel@univie.ac.at
Web: http://www.bpc.univie.ac.at

^b Universität Wien, Fakultät für Chemie, Institut für Anorganische Chemie, Währinger Str. 42, 1090 Wien, Austria

Abstract

Na₂[TMA]₂[Ni(OH)₃W₆O₁₈(OCH₂)₃CCH₂OH]·9H₂O represents the first covalent tris-functionalized Anderson-type heteropolytungstate and was characterized by single-crystal X-ray diffraction, electrospray ionization mass spectrometry, TGA and IR spectroscopy. Zeta potential measurements in solutions containing human serum albumin were performed to investigate electrostatic interactions with [Ni(OH)₃W₆O₁₈(OCH₂)₃CCH₂OH]⁴⁻.

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Article information

DOI: https://doi.org/10.1039/C6CC04326G
Article type: Communication
Submitted: 23 May 2016
Accepted: 15 Jun 2016
First published: 15 Jun 2016
This article is Open Access

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Chem. Commun., 2016,52, 9263-9266

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[Ni(OH)₃W₆O₁₈(OCH₂)₃CCH₂OH]⁴⁻: the first tris-functionalized Anderson-type heteropolytungstate

N. I. Gumerova, A. Roller and A. Rompel, Chem. Commun., 2016, 52, 9263 DOI: 10.1039/C6CC04326G

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