Issue 62, 2016

Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal–organic polyhedra

Abstract

Unprecedented Anderson-like alkoxo-polyoxovanadate [V6O6(OCH3)96-SO4)(COO)3]2− polyanions can serve as 3-connected second building units (SBUs) that assemble with dicarboxylate or tricarboxylate ligands to form a new family of metal organic tetrahedrons of V4E6 and V4F4 type (V = vertex, E = edge, and F = face). To our knowledge, this alkoxo-polyoxovanadate-based SBU is the first ever reported.

Graphical abstract: Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal–organic polyhedra

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2016
Accepted
24 Jun 2016
First published
24 Jun 2016

Chem. Commun., 2016,52, 9632-9635

Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal–organic polyhedra

Y. Zhang, X. Wang, S. Li, Y. Gong, B. Song, K. Shao and Z. Su, Chem. Commun., 2016, 52, 9632 DOI: 10.1039/C6CC04583A

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