Issue 77, 2016
From the journal:

Chemical Communications

A metal–organic framework with rod secondary building unit based on the Boerdijk–Coxeter helix†

Qiong Xiao,‡a   Yuan Wu,‡a   Mian Li,a   Michael O'Keeffe*b  and  Dan Li*ac  

* Corresponding authors

a Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, People's Republic of China
E-mail: dli@stu.edu.cn

b School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, USA
E-mail: mokeeffe@asu.edu

c College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, People's Republic of China

Abstract

The renowned aperiodic Boerdijk–Coxeter helix is identified, with a modified, periodic form, in a MOF named ROD-1 [formulated as Cd(L), H2L = (3,5-dimethyl-1H-(pyrazol-4-yl)-methylene)benzoic acid], which exhibits unusual gas adsorption behaviours attributed to guest–guest interactions, and also interesting structural dynamics responding to temperature variation and gas adsorption.

Graphical abstract: A metal–organic framework with rod secondary building unit based on the Boerdijk–Coxeter helix

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Article information

DOI
https://doi.org/10.1039/C6CC04912E
Article type
Communication
Submitted
12 Jun 2016
Accepted
22 Aug 2016
First published
22 Aug 2016

Chem. Commun., 2016,52, 11543-11546

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A metal–organic framework with rod secondary building unit based on the Boerdijk–Coxeter helix

Q. Xiao, Y. Wu, M. Li, M. O'Keeffe and D. Li, Chem. Commun., 2016, 52, 11543 DOI: 10.1039/C6CC04912E

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