Issue 71, 2016
From the journal:

Chemical Communications

Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties†

Makoto Saikawa,a   Takashi Nakamura,a   Junji Uchida,a   Masaki Yamamuraa  and  Tatsuya Nabeshima*a  

* Corresponding authors

a Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
E-mail: nabesima@chem.tsukuba.ac.jp

Abstract

A macrocyclic bisBODIPY (bis(boron-dipyrromethene)) complex [1B2] with a figure-of-eight helicity was synthesized and successfully resolved. [1B2] was proven to be one of the most efficient red-emitting CPL (circularly polarized luminescence) fluorophores reported to date (λ = 663 nm, |glum| = 9 × 10−3, ΦF = 0.58).

Graphical abstract: Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties

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Article information

DOI
https://doi.org/10.1039/C6CC05439K
Article type
Communication
Submitted
30 Jun 2016
Accepted
21 Jul 2016
First published
21 Jul 2016

Chem. Commun., 2016,52, 10727-10730

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Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties

M. Saikawa, T. Nakamura, J. Uchida, M. Yamamura and T. Nabeshima, Chem. Commun., 2016, 52, 10727 DOI: 10.1039/C6CC05439K

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