A microporous Cu-MOF with optimized open metal sites and pore spaces for high gas storage and active chemical fixation of CO2

Chao-Ying Gao; Hong-Rui Tian; Jing Ai; Lei-Jiao Li; Song Dang; Ya-Qian Lan; Zhong-Ming Sun

doi:10.1039/C6CC05845K

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A microporous Cu-MOF with optimized open metal sites and pore spaces for high gas storage and active chemical fixation of CO₂†

Chao-Ying Gao,^abc Hong-Rui Tian,^b Jing Ai,^bc Lei-Jiao Li,^b Song Dang,^b Ya-Qian Lan^d and Zhong-Ming Sun*^b

Author affiliations

* Corresponding authors

^a College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao 02800, P. R. China

^b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Science, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China
E-mail: szm@ciac.ac.cn
Web: http://zhongmingsun.weebly.com

^c University of Chinese Academy of Science, Beijing 100049, P. R. China

^d School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, P. R. China

Abstract

A microporous Cu-MOF with optimized open metal sites and pore space was constructed based on a designed bent ligand; it exhibits high-capacity multiple gas storage under atmospheric pressure and efficient catalytic activity for chemical fixation of CO₂ under mild conditions.

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Article information

DOI: https://doi.org/10.1039/C6CC05845K
Article type: Communication
Submitted: 15 Jul 2016
Accepted: 15 Aug 2016
First published: 15 Aug 2016

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Chem. Commun., 2016,52, 11147-11150

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A microporous Cu-MOF with optimized open metal sites and pore spaces for high gas storage and active chemical fixation of CO₂

C. Gao, H. Tian, J. Ai, L. Li, S. Dang, Y. Lan and Z. Sun, Chem. Commun., 2016, 52, 11147 DOI: 10.1039/C6CC05845K

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Chemical Communications