NdBaScO4: aristotype of a new family of geometric ferroelectrics?

Amber K. Cochrane; Michael Telfer; Charlotte A. L. Dixon; Weiguo Zhang; P. Shiv Halasyamani; Eric Bousquet; Philip Lightfoot

doi:10.1039/C6CC05940F

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NdBaScO₄: aristotype of a new family of geometric ferroelectrics?†

Amber K. Cochrane,^a Michael Telfer,^a Charlotte A. L. Dixon,^a Weiguo Zhang,^b P. Shiv Halasyamani,^b Eric Bousquet^c and Philip Lightfoot*^a

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* Corresponding authors

^a School of Chemistry and EaStChem, University of St Andrews, St Andrews, Fife, UK
E-mail: pl@st-and.ac.uk

^b Department of Chemistry, University of Houston, 112 Fleming Building, Houston, TX 77204-5003, USA

^c Université de Liège, CESAM, Institut de Physique B5a, Allée du 6 Août, 19, B-4000 Sart Tilman, Belgium

Abstract

NdBaScO₄ represents the aristotype structure of a new series of 〈110〉-cut layered perovskites; it is suggested that compositional fine-tuning is likely to produce a family of new geometric ferroelectrics, driven primarily by octahedral tilting.

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Article information

DOI: https://doi.org/10.1039/C6CC05940F
Article type: Communication
Submitted: 19 Jul 2016
Accepted: 15 Aug 2016
First published: 15 Aug 2016

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Chem. Commun., 2016,52, 10980-10983

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NdBaScO₄: aristotype of a new family of geometric ferroelectrics?

A. K. Cochrane, M. Telfer, C. A. L. Dixon, W. Zhang, P. S. Halasyamani, E. Bousquet and P. Lightfoot, Chem. Commun., 2016, 52, 10980 DOI: 10.1039/C6CC05940F

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