Issue 73, 2016
From the journal:

Chemical Communications

Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere†

Yubin M. Kwon,a   Mayra Delgado,a   Lev N. Zakharov,b   Takele Sedac  and  John D. Gilbertson*a  

* Corresponding authors

a Department of Chemistry, Western Washington University, Bellingham, WA, USA
E-mail: John.gilbertson@wwu.edu

b Department of Chemistry, University of Oregon, Eugene, Oregon, USA

c Department of Physics, Western Washington University, Bellingham, WA, USA

Abstract

The proton-responsive pyridinediimine ligand, DEAPDI (where DEAPDI = [(2,6-iPrC6H3)(N[double bond, length as m-dash]CMe)(N(Et)2C2H4)(N[double bond, length as m-dash]CMe)C5H3N]) was utilized for the reduction of NO2− to NO. Nitrite reduction is facilitated by the protonated secondary coordination sphere coupled with the ligand-based redox-active sites of [Fe(HDEAPDI)(CO)2]+ and results in the formation of the {Fe(NO)2}9 DNIC, [Fe(DEAPDI)(NO)2]+.

Graphical abstract: Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere

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Article information

DOI
https://doi.org/10.1039/C6CC05962G
Article type
Communication
Submitted
20 Jul 2016
Accepted
16 Aug 2016
First published
16 Aug 2016

Chem. Commun., 2016,52, 11016-11019

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Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere

Y. M. Kwon, M. Delgado, L. N. Zakharov, T. Seda and J. D. Gilbertson, Chem. Commun., 2016, 52, 11016 DOI: 10.1039/C6CC05962G

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