An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents

Vianney Regnier; Florian Molton; Christian Philouze; David Martin

doi:10.1039/C6CC06260A

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An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents†

Vianney Regnier,^a Florian Molton,^a Christian Philouze^a and David Martin

*^a

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* Corresponding authors

^a Département de Chimie Moléculaire, UMR CNRS 5250, Université Grenoble-Alpes B. P. 53, 38041 Cedex 9 Grenoble, France
E-mail: david.martin@univ-grenoble-alpes.fr

Abstract

We report an experimental and theoretical study of the 1,1,3,3-tetrakis-di(methylamino)oxyallyl radical cation. Despite simple substituents with minimal steric hindrance, this radical was found to be stable under an inert atmosphere and persistent for several hours in well-aerated solutions.

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DOI: https://doi.org/10.1039/C6CC06260A
Article type: Communication
Submitted: 28 Jul 2016
Accepted: 24 Aug 2016
First published: 25 Aug 2016

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Chem. Commun., 2016,52, 11422-11425

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An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents

V. Regnier, F. Molton, C. Philouze and D. Martin, Chem. Commun., 2016, 52, 11422 DOI: 10.1039/C6CC06260A

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Chemical Communications

An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents†

Abstract

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An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents

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