Issue 85, 2016
From the journal:

Chemical Communications

A racemate-rules effect supramolecular polymer for ee determination of malic acid in the high ee region†

Xuan-Xuan Chen,ab   Yun-Bao Jiang*b  and  Eric V. Anslyn*a  

* Corresponding authors

a Department of Chemistry, University of Texas at Austin, Austin, TX 78712, USA
E-mail: anslyn@austin.utexas.edu

b Department of Chemistry, College of Chemistry and Chemical Engineering, MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, China
E-mail: ybjiang@xmu.edu.cn

Abstract

A supramolecular polymeric system that shows an unusual “racemate-rules” chiroptical property, an effect opposite to the well-known “majority-rules”, has been utilized for accurate determination of malic acid enantiopurity at high ee values.

Graphical abstract: A racemate-rules effect supramolecular polymer for ee determination of malic acid in the high ee region

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Article information

DOI
https://doi.org/10.1039/C6CC06716F
Article type
Communication
Submitted
15 Aug 2016
Accepted
04 Oct 2016
First published
04 Oct 2016

Chem. Commun., 2016,52, 12669-12671

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A racemate-rules effect supramolecular polymer for ee determination of malic acid in the high ee region

X. Chen, Y. Jiang and E. V. Anslyn, Chem. Commun., 2016, 52, 12669 DOI: 10.1039/C6CC06716F

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