Issue 79, 2016

Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site

Abstract

The palladium diphosphinoboryl pincer [{(o-PPh2C6H4)2B}PdIII] 8 was prepared from the diphosphinoborane complex 6a. The boryl functionality of the pincer displayed ambiphilic properties allowing: (1) coordination of Lewis basic pyridines to the boryl site and (2) access to palladium diphosphinoborane complex derivatives.

Graphical abstract: Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site

Supplementary files

Article information

Article type
Communication
Submitted
29 Aug 2016
Accepted
05 Sep 2016
First published
06 Sep 2016

Chem. Commun., 2016,52, 11823-11826

Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site

D. Schuhknecht, F. Ritter and M. E. Tauchert, Chem. Commun., 2016, 52, 11823 DOI: 10.1039/C6CC07079E

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