Issue 99, 2016
From the journal:

Chemical Communications

Chirality sensing and discrimination of lysine derivatives in water with a dyn[4]arene†

Laurent Vial,*a   Melissa Dumartin,b   Marion Donnier-Maréchal,b   Florent Perret,b   Jean-Patrick Francoiaa  and  Julien Leclaire*b  

* Corresponding authors

a Institut des Biomolécules Max Mousseron, UMR 5247 CNRS – Université de Montpellier – ENSCM, Place Eugène Bataillon, 34296 Montpellier cedex 5, France
E-mail: laurent.vial@univ-montp2.fr

b Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, UMR 5246 CNRS – Université Claude Bernard Lyon 1 – CPE Lyon – INSA, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne cedex, France
E-mail: julien.leclaire@univ-lyon1.fr

Abstract

The asymmetric deformation of a dyn[4]arene upon the binding of various lysine derivatives leads to distinct induced circular dichroism outputs in buffered water, which can be exploited not only for the determination of their enantiomeric excesses, but also for their classification by linear discriminant analysis.

Graphical abstract: Chirality sensing and discrimination of lysine derivatives in water with a dyn[4]arene

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Article information

DOI
https://doi.org/10.1039/C6CC07713G
Article type
Communication
Submitted
22 Sep 2016
Accepted
15 Nov 2016
First published
15 Nov 2016

Chem. Commun., 2016,52, 14219-14221

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Chirality sensing and discrimination of lysine derivatives in water with a dyn[4]arene

L. Vial, M. Dumartin, M. Donnier-Maréchal, F. Perret, J. Francoia and J. Leclaire, Chem. Commun., 2016, 52, 14219 DOI: 10.1039/C6CC07713G

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