Issue 97, 2016

Palladium catalyzed selective distal C–H olefination of biaryl systems

Abstract

Palladium catalyzed selective distal C–H activation with nitrile based templates has been of significant research interest in recent times. In this report, we disclose the distal C–H olefination of biphenyl systems with high regio- and stereo-selectivity and useful synthetic yields. The utility of this method has been demonstrated through its wide olefin scope, its operation at the gram scale and the easy removal/recovery of the directing group.

Graphical abstract: Palladium catalyzed selective distal C–H olefination of biaryl systems

Supplementary files

Article information

Article type
Communication
Submitted
27 Sep 2016
Accepted
09 Nov 2016
First published
09 Nov 2016

Chem. Commun., 2016,52, 14003-14006

Palladium catalyzed selective distal C–H olefination of biaryl systems

S. Maity, E. Hoque, U. Dhawa and D. Maiti, Chem. Commun., 2016, 52, 14003 DOI: 10.1039/C6CC07861C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements