SCHEDULED MAINTENANCE
A novel copper-catalyzed carbonylative acetylation of amines has been developed. With peroxide as the oxidant as well as the methyl source with a copper catalyst under CO pressure, good yields of N-acetyl amides could be obtained. Notably, this is the first example of carbonylative acetylation.
Y. Li, C. Wang, F. Zhu, Z. Wang, J. François Soulé, P. H. Dixneuf and X. Wu, Chem. Commun., 2017, 53, 142 DOI: 10.1039/C6CC08929A
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