Issue 3, 2017
From the journal:

Chemical Communications

Guest-induced SC–SC transformation within the first K/Cd heterodimetallic triazole complex: a luminescent sensor for high-explosives and cyano molecules†

Ying Wang,*ab   Wei Jia,a   Ran Chen,a   Xiao-Jun Zhao*a  and  Zhong-Liang Wang*c  

* Corresponding authors

a Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China
E-mail: wangying790601@163.com

b Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

c Tianjin Key Laboratory of Water Resources and Environment, Tianjin Normal University, Tianjin 300387, China

Abstract

The first K/Cd heterodimetallic complex {[Cd1.5(TTPE)1.5Cl3K(H2O)3]·3H2O}n (1b) based on triazole has been generated from {[Cd(TTPE)(HCOO)](NO3)·3DMAC·H2O}n (1) during the ion- and solvent-exchange experiment in an irreversible SC–SC transformation. Based on its luminescence properties, we have, for the first time, demonstrated that 1b is a heterodimetallic sensor for detection of high-explosives and cyano molecules.

Graphical abstract: Guest-induced SC–SC transformation within the first K/Cd heterodimetallic triazole complex: a luminescent sensor for high-explosives and cyano molecules

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Article information

DOI
https://doi.org/10.1039/C6CC09566F
Article type
Communication
Submitted
01 Dec 2016
Accepted
08 Dec 2016
First published
19 Dec 2016

Chem. Commun., 2017,53, 636-639

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Guest-induced SC–SC transformation within the first K/Cd heterodimetallic triazole complex: a luminescent sensor for high-explosives and cyano molecules

Y. Wang, W. Jia, R. Chen, X. Zhao and Z. Wang, Chem. Commun., 2017, 53, 636 DOI: 10.1039/C6CC09566F

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