Issue 43, 2016
From the journal:

CrystEngComm

Thermal expansion properties of three isostructural co-crystals composed of isosteric components: interplay between halogen and hydrogen bonds†

Kristin M. Hutchins,a   Katherine A. Kummer,b   Ryan H. Groeneman,*b   Eric W. Reinheimer,c   Michael A. Sinnwell,a   Dale C. Swensona  and  Leonard R. MacGillivray*a  

* Corresponding authors

a Department of Chemistry, University of Iowa, Iowa City, IA, USA
E-mail: len-macgillivray@uiowa.edu
Tel: (+1) 319 335 3504

b Department of Biological Sciences, Webster University, St. Louis, MO, USA
E-mail: ryangroeneman19@webster.edu
Tel: (+1) 314 246 7466

c Department of Chemistry and Biochemistry, W. M. Keck Foundation Center for Molecular Structure, California State University San Marcos, San Marcos, CA 92096, USA

Abstract

Co-crystallization of a symmetrical azo bipyridine with isosteric resorcinols affords isostructural co-crystals that exhibit linear thermal expansion along each axis. The thermal expansions involve interplay between intra-layer halogen and hydrogen bonds.

Graphical abstract: Thermal expansion properties of three isostructural co-crystals composed of isosteric components: interplay between halogen and hydrogen bonds

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Article information

DOI
https://doi.org/10.1039/C6CE01674J
Article type
Communication
Submitted
29 Jul 2016
Accepted
22 Aug 2016
First published
23 Aug 2016

CrystEngComm, 2016,18, 8354-8357

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Thermal expansion properties of three isostructural co-crystals composed of isosteric components: interplay between halogen and hydrogen bonds

K. M. Hutchins, K. A. Kummer, R. H. Groeneman, E. W. Reinheimer, M. A. Sinnwell, D. C. Swenson and L. R. MacGillivray, CrystEngComm, 2016, 18, 8354 DOI: 10.1039/C6CE01674J

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