Collision energy dependence of state-to-state differential cross sections for rotationally inelastic scattering of H2O by He

Abstract

The inelastic scattering of H₂O by He as a function of collision energy in the range 381 cm⁻¹ to 763 cm⁻¹ at an energy interval of approximately 100 cm⁻¹ has been investigated in a crossed beam experiment using velocity map imaging. Change in collision energy was achieved by varying the collision angle between the H₂O and He beam. We measured the state-to-state differential cross section (DCS) of scattered H₂O products for the final rotational states J_KaKc = 1₁₀, 1₁₁, 2₂₁ and 4₁₄. Rotational excitation of H₂O is probed by (2 + 1) resonance enhanced multiphoton ionization (REMPI) spectroscopy. DCS measurements over a wide range of collision energies allowed us to probe the H₂O–He potential energy surface (PES) with greater detail than in previous work. We found that a classical approximation of rotational rainbows can predict the collision energy dependence of the DCS. Close-coupling quantum mechanical calculations were used to produce DCS and partial cross sections. The forward–backward ratio (FBR), is introduced here to compare the experimental and theoretical DCS. Both theory and experiments suggest that an increase in the collision energy is accompanied with more forward scattering.