Issue 23, 2016
From the journal:

Dalton Transactions

The structure and in situ synthesis investigation of isomorphic mononuclear molecular metal phenylphosphonates†

Manuel Wilke,ab   Ana Guilherme Buzanich,a   Uwe Reinholz,a   Klaus Rademannb  and  Franziska Emmerling*a  

* Corresponding authors

a Federal Institute for Materials Research and Testing (BAM), Richard-Willstaetter-Str. 11, 12489 Berlin, Germany
E-mail: franziska.emmerling@bam.de
Fax: +49-30-8104-7-1133
Tel: +49-30-8104-1133

b Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germany

Abstract

We describe a fast and effective synthesis for molecular metal phosphonates. Isomorphic compounds [M(II)(HO3PPh)2(H2O3PPh)2(H2O)2] (M = Mn (1), Co (2), Ni (3); Ph = C6H5) were obtained by grinding. The complexes are mononuclear compounds containing neutral and monodeprotonated phenylphosphonic acid and water as ligands. The crystal structures were determined using powder X-ray diffraction (PXRD) data and validated by extended X-ray absorption fine structure (EXAFS) data. Combined synchrotron XRD measurements and Raman spectroscopy were conducted for investigating the reactions in situ. Based on these data, the intermediates were characterized and the formation mechanism was derived.

Graphical abstract: The structure and in situ synthesis investigation of isomorphic mononuclear molecular metal phenylphosphonates

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Article information

DOI
https://doi.org/10.1039/C6DT00787B
Article type
Paper
Submitted
27 Feb 2016
Accepted
28 Apr 2016
First published
28 Apr 2016
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2016,45, 9460-9467

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The structure and in situ synthesis investigation of isomorphic mononuclear molecular metal phenylphosphonates

M. Wilke, A. G. Buzanich, U. Reinholz, K. Rademann and F. Emmerling, Dalton Trans., 2016, 45, 9460 DOI: 10.1039/C6DT00787B

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