Issue 31, 2016

Ferromagnetic coupling mediated by Co⋯π non-covalent contacts in a pentacoordinate Co(ii) compound showing field-induced slow relaxation of magnetization

Abstract

[CoII(dpt)(NCS)2], where dpt = bis(3-aminopropyl)amine, was identified as a pentacoordinate CoII compound showing field-induced slow relaxation of magnetization. Furthermore, intermolecular ferromagnetic coupling mediated by Co⋯π non-covalent contacts, where π orbitals originate from the thiocyanato ligand, is reported for the first time.

Graphical abstract: Ferromagnetic coupling mediated by Co⋯π non-covalent contacts in a pentacoordinate Co(ii) compound showing field-induced slow relaxation of magnetization

Supplementary files

Article information

Article type
Paper
Submitted
21 Apr 2016
Accepted
12 Jul 2016
First published
12 Jul 2016
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2016,45, 12479-12482

Ferromagnetic coupling mediated by Co⋯π non-covalent contacts in a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization

I. Nemec, R. Herchel and Z. Trávníček, Dalton Trans., 2016, 45, 12479 DOI: 10.1039/C6DT01539E

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