Issue 37, 2016

Insights into small molecule activation by multinuclear first-row transition metal cyclophanates

Abstract

The rational design of trimetallic transition metal clusters supported by a trinucleating cyclophane ligand, L3−, and the reactivities of these complexes with dinitrogen and carbon dioxide are discussed. Emphasis is placed on the differences in the observed reactivity between these trimetallic cyclophane complexes and that of the mono- and dinuclear transition metal compounds.

Graphical abstract: Insights into small molecule activation by multinuclear first-row transition metal cyclophanates

Article information

Article type
Perspective
Submitted
11 May 2016
Accepted
14 Jul 2016
First published
21 Jul 2016

Dalton Trans., 2016,45, 14499-14507

Insights into small molecule activation by multinuclear first-row transition metal cyclophanates

D. M. Ermert and L. J. Murray, Dalton Trans., 2016, 45, 14499 DOI: 10.1039/C6DT01857B

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