Issue 38, 2016

Synthesis, structures, and magnetic properties of metal–organic polyhedra based on unprecedented {V7} isopolyoxometalate clusters

Abstract

Two isostructural vanadium-based metal–organic polyhedra (denoted as VMOP-16 and VMOP-17) were synthesized by a solvothermal method, which are built from unprecedented {V7} isopolyoxometalate clusters and dicarboxylate ligands. To our knowledge, the {V7} second building unit is reported for the first time and features the highest nuclearity of vanadium–oxygen clusters compared with reported vanadium-based MOPs.

Graphical abstract: Synthesis, structures, and magnetic properties of metal–organic polyhedra based on unprecedented {V7} isopolyoxometalate clusters

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2016
Accepted
24 Aug 2016
First published
25 Aug 2016

Dalton Trans., 2016,45, 14898-14901

Synthesis, structures, and magnetic properties of metal–organic polyhedra based on unprecedented {V7} isopolyoxometalate clusters

Y. Zhang, S. Li, X. Wang, Y. Gong, K. Shao and Z. Su, Dalton Trans., 2016, 45, 14898 DOI: 10.1039/C6DT02764D

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