Issue 48, 2016
From the journal:

Dalton Transactions

Controlling the magnetic properties of dysprosium metallofullerene within metal–organic frameworks†

Yongjian Li,ab   Taishan Wang,*a   Haibing Meng,ab   Chong Zhao,a   Mingzhe Nie,ab   Li Jianga  and  Chunru Wang*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, 100190 Beijing, China
E-mail: wangtais@iccas.ac.cn, crwang@iccas.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Magnetic endohedral metallofullerenes represent a new family of single-molecule magnets with a spherical form and solid framework. In this manuscript, we illustrate the controllable quantum tunneling of magnetism for metallofullerene DySc2N@C80 by means of molecule encapsulation in a porous metal–organic framework (MOF-177) with strong host–guest interactions.

Graphical abstract: Controlling the magnetic properties of dysprosium metallofullerene within metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C6DT04180A
Article type
Communication
Submitted
01 Nov 2016
Accepted
16 Nov 2016
First published
17 Nov 2016

Dalton Trans., 2016,45, 19226-19229

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Controlling the magnetic properties of dysprosium metallofullerene within metal–organic frameworks

Y. Li, T. Wang, H. Meng, C. Zhao, M. Nie, L. Jiang and C. Wang, Dalton Trans., 2016, 45, 19226 DOI: 10.1039/C6DT04180A

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