Issue 8, 2017

Metal–organic frameworks utilising an interlocked, hexadentate linker containing a tetra-carboxylate axle and a bis(pyridine) wheel

Abstract

A [2]rotaxane linker was synthesized which combines an H-shaped axle containing four 3-carboxyphenyl groups and a macrocyclic wheel with two 4-pyridyl groups. Metal–organic framework materials were prepared with CuII and ZnII ions X-ray structures show that the materials contain unique frameworks that are threaded solely due to the interpenetrated nature of the linker.

Graphical abstract: Metal–organic frameworks utilising an interlocked, hexadentate linker containing a tetra-carboxylate axle and a bis(pyridine) wheel

Supplementary files

Article information

Article type
Paper
Submitted
05 Dec 2016
Accepted
27 Jan 2017
First published
07 Feb 2017

Dalton Trans., 2017,46, 2462-2470

Metal–organic frameworks utilising an interlocked, hexadentate linker containing a tetra-carboxylate axle and a bis(pyridine) wheel

G. Gholami, G. Baggi, K. Zhu and S. J. Loeb, Dalton Trans., 2017, 46, 2462 DOI: 10.1039/C6DT04596K

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