Issue 3, 2017
From the journal:

New Journal of Chemistry

Chiral Zn–salen complexes: a new class of fluorescent receptors for enantiodiscrimination of chiral amines†‡

Roberta Puglisi,a   Francesco P. Ballistreri,a   Chiara M. A. Gangemi,a   Rosa Maria Toscano,a   Gaetano A. Tomaselli, ORCID logo a   Andrea Pappalardo*ab  and  Giuseppe Trusso Sfrazzetto ORCID logo *a  

* Corresponding authors

a Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, Catania, Italy
E-mail: giuseppe.trusso@unict.it

b INSTM Udr of Catania, Viale Andrea Doria 6, Catania, Italy

Abstract

The first example of fluorescent chiral Zn–salen hosts, able to efficiently recognise chiral amines via non-covalent interactions, is reported here. The host–guest interactions have been characterised by 2D-NMR spectroscopy in order to elucidate the origin of enantioselectivity.

Graphical abstract: Chiral Zn–salen complexes: a new class of fluorescent receptors for enantiodiscrimination of chiral amines

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Article information

DOI
https://doi.org/10.1039/C6NJ03592B
Article type
Letter
Submitted
16 Nov 2016
Accepted
21 Dec 2016
First published
23 Dec 2016

New J. Chem., 2017,41, 911-915

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Chiral Zn–salen complexes: a new class of fluorescent receptors for enantiodiscrimination of chiral amines

R. Puglisi, F. P. Ballistreri, C. M. A. Gangemi, R. M. Toscano, G. A. Tomaselli, A. Pappalardo and G. T. Sfrazzetto, New J. Chem., 2017, 41, 911 DOI: 10.1039/C6NJ03592B

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