Synthesis and self-assembly of a D3h symmetric polycyclic aromatic hydrocarbon into a rigid 2D honeycomb network

Liyan Zhang; Jinling Li; Shuhai Qiu; Xiaobo Huang; Zebing Zeng

doi:10.1039/C6NJ03962F

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Synthesis and self-assembly of a D_3h symmetric polycyclic aromatic hydrocarbon into a rigid 2D honeycomb network†

Liyan Zhang,‡^a Jinling Li,‡^b Shuhai Qiu,^a Xiaobo Huang

^c and Zebing Zeng

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China
E-mail: zbzeng@hnu.edu.cn

^b School of Material Science & Engineering, Henan University of Technology, Zhengzhou 450001, Henan, P. R. China

^c College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China

Abstract

D _3h symmetric hexa-peri-hexabenzocoronene substituted by three carboxylic acid groups (HBC-COOH) was synthesized. HBC-COOH formed a rigid two-dimensional (2D) honeycomb network at a solid–liquid interface via intermolecular hydrogen bonding interactions. Guest molecules such as coronene can fill the cavities of this porous 2D network.

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Article information

DOI: https://doi.org/10.1039/C6NJ03962F
Article type: Paper
Submitted: 16 Dec 2016
Accepted: 06 Mar 2017
First published: 09 Mar 2017

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New J. Chem., 2017,41, 3260-3264

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Synthesis and self-assembly of a D_3h symmetric polycyclic aromatic hydrocarbon into a rigid 2D honeycomb network

L. Zhang, J. Li, S. Qiu, X. Huang and Z. Zeng, New J. Chem., 2017, 41, 3260 DOI: 10.1039/C6NJ03962F

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