Autocatalytic synthesis of multifunctional precursors for fabricating silica microspheres with well-dispersed Ag and Co3O4 nanoparticles

Abstract

Herein, an autocatalytic route to fabricate dual metal ion-equipped organic/inorganic hybrid silica, an ideal precursor for multifunctional silica-based composites integrated with well-dispersed Ag and Co₃O₄ nanoparticles was demonstrated. Significantly, by rational selection of reactants, such dual metal ion-equipped organic/inorganic hybrid silica can be synthesized through successive spontaneous reactions under near neutral conditions without an additional catalyst. Both the Ag⁺ and Co²⁺ ions are introduced into silica by chemical bonds, which favor the formation of small-sized and well-dispersed Ag and Co₃O₄ nanoparticles without aggregation in the entire silica matrix. After calcination, multifunctional silica composites equipped with well-dispersed Ag and Co₃O₄ nanoparticles were obtained. The as-obtained silica composites, as indicated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), have a spherical morphology and smooth surface. TEM tests also reveal the well dispersed fashion of Ag and Co₃O₄ nanoparticles. In addition, the obtained Ag–Co₃O₄@SiO₂ composites exhibit good catalytic performance in the reduction of methylene blue (MB) with NaBH₄ as a reducing agent, and can be readily recycled by an external magnetic field due to their superparamagnetic properties.