Issue 4, 2017
From the journal:

Organic & Biomolecular Chemistry

Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene – redox-controlled generation of a large PAH core†

Søren Lindbæk Broman,a   Cecilie Lindholm Andersen,a   Tanguy Jousselin-Oba,b   Mads Mansø,a   Ole Hammerich,a   Michel Frigoli*b  and  Mogens Brøndsted Nielsen ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark
E-mail: mbn@chem.ku.dk

b UMR CNRS 8180, UVSQ, Institut Lavoisier de Versailles, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
E-mail: michel.frigoli@uvsq.fr

Abstract

Two tetraceno[2,1,12,11-opqra]tetracene-extended tetrathia-fulvalenes were prepared and found to undergo reversible conversion into their planar polycyclic aromatic hydrocarbons (PAHs) upon electrochemical oxidation – at potentials probing the best valence bond representations.

Graphical abstract: Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene – redox-controlled generation of a large PAH core

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Article information

DOI
https://doi.org/10.1039/C6OB02666D
Article type
Communication
Submitted
06 Dec 2016
Accepted
22 Dec 2016
First published
22 Dec 2016
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2017,15, 807-811

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Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene – redox-controlled generation of a large PAH core

S. L. Broman, C. L. Andersen, T. Jousselin-Oba, M. Mansø, O. Hammerich, M. Frigoli and M. B. Nielsen, Org. Biomol. Chem., 2017, 15, 807 DOI: 10.1039/C6OB02666D

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