Issue 6, 2017

Towards hydroxamic acid linked zirconium metal–organic frameworks

Abstract

Solvent-assisted linker exchange (SALE) is performed on the Zr-based metal–organic framework (MOF), UiO-66, to exchange benzene-1,4-dicarboxylate with benzene-1,4-dihydroxamate linkers. Characterization of the material before and after SALE is performed using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), nitrogen adsorption, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The stability of the parent and daughter material is evaluated at pH 1 and 12 and the structural integrity evaluated by PXRD, mass balance and porosity measurements.

Graphical abstract: Towards hydroxamic acid linked zirconium metal–organic frameworks

Supplementary files

Article information

Article type
Research Article
Submitted
15 Dec 2016
Accepted
23 Jan 2017
First published
30 Jan 2017

Mater. Chem. Front., 2017,1, 1194-1199

Towards hydroxamic acid linked zirconium metal–organic frameworks

C. F. Pereira, A. J. Howarth, N. A. Vermeulen, F. A. Almeida Paz, J. P. C. Tomé, J. T. Hupp and O. K. Farha, Mater. Chem. Front., 2017, 1, 1194 DOI: 10.1039/C6QM00364H

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