Issue 5, 2017

Quasi-planar diazadithio and diazodiseleno[8]circulenes: synthesis, structures and properties

Abstract

Diazadithio and diazadiseleno[8]circulenes were synthesized in good yields through a non-pyrolytic cyclization starting from nitrogen-bridged tetraphenylene. Their structures were unambiguously confirmed by X-ray crystallographic analyses. Photophysical, electrochemical and computational investigations of these [8]circulenes suggested their potential applications in inorganic materials.

Graphical abstract: Quasi-planar diazadithio and diazodiseleno[8]circulenes: synthesis, structures and properties

Supplementary files

Article information

Article type
Research Article
Submitted
26 Oct 2016
Accepted
05 Dec 2016
First published
07 Dec 2016

Org. Chem. Front., 2017,4, 682-687

Quasi-planar diazadithio and diazodiseleno[8]circulenes: synthesis, structures and properties

X. Xiong, C. Deng, Z. Li, X. Peng and H. N. C. Wong, Org. Chem. Front., 2017, 4, 682 DOI: 10.1039/C6QO00662K

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