Issue 46, 2016, Issue in Progress

A remarkable chiral recognition of racemic Mosher's acid salt by naturally derived chiral ionic liquids using 19F NMR spectroscopy

Abstract

A new class of D-xylose derived imidazolium-based chiral ionic liquids were designed and synthesized via simple tuning approaches. The developed chiral ionic liquids were tested for their chiral recognition properties with racemic Mosher's acid salt using 19F NMR spectroscopy. For the first time, we demonstrate the excellent enantioselective discrimination of the racemic salt using significantly less equivalents of carbohydrate derived chiral ionic liquids. We have determined the enantiomeric excess values of non-racemic mixtures of Mosher's acid salts using 19F NMR spectroscopy.

Graphical abstract: A remarkable chiral recognition of racemic Mosher's acid salt by naturally derived chiral ionic liquids using 19F NMR spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
30 Jan 2016
Accepted
31 Mar 2016
First published
01 Apr 2016

RSC Adv., 2016,6, 39758-39761

A remarkable chiral recognition of racemic Mosher's acid salt by naturally derived chiral ionic liquids using 19F NMR spectroscopy

R. Jayachandra and S. R. Reddy, RSC Adv., 2016, 6, 39758 DOI: 10.1039/C6RA02792J

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