Directed by in situ methylated nicotinohydrazide (MNH2+), two iodoargentate hybrids, {[MNH][Ag3I5]}n (1) and {[MNH][Ag7I9]}n (2), have been synthesized via modulating the organic/inorganic ratio. They exhibit rare structure-dependent electron transfer (ET) photochromism as confirmed by EPR, XPS, and UV-vis absorption spectra.
J. Shen, F. Wang, X. Li, T. Yu, P. Hao and Y. Fu, RSC Adv., 2016, 6, 98916 DOI: 10.1039/C6RA20084B
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