An open route to asymmetric substituted Al–Al bonds using Al(I)- and Al(III)-precursors

Bin Li; Subrata Kundu; Hongping Zhu; Helena Keil; Regine Herbst-Irmer; Dietmar Stalke; Gernot Frenking; Diego M. Andrada; Herbert W. Roesky

doi:10.1039/C7CC00325K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

An open route to asymmetric substituted Al–Al bonds using Al(i)- and Al(iii)-precursors†

Bin Li,^ab Subrata Kundu,^a Hongping Zhu,*^b Helena Keil,^a Regine Herbst-Irmer,^a Dietmar Stalke,

*^a Gernot Frenking,*^c Diego M. Andrada^c and Herbert W. Roesky

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany
E-mail: hroesky@gwdg.de, dstalke@chemie.uni-goettingen.de

^b State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: hpzhu@xmu.edu.cn

^c Fachbereich Chemie, Philipps-Universtät Marburg, Hans-Meerwein-Str., 35032 Marburg, Germany
E-mail: frenking@chemie.uni-marburg.de

Abstract

The reaction of LAl: (L = HC[C(Me)N(Ar)]₂, Ar = 2,6-iPr₂C₆H₃) and cAAC:→AlX₃ (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(II)–Al(II) compounds LAl(X)–Al(X)₂–cAAC [X = Cl (2a); I (2b)]. In these dialuminum(II) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7CC00325K
Article type: Communication
Submitted: 13 Jan 2017
Accepted: 27 Jan 2017
First published: 27 Jan 2017

Download Citation

Chem. Commun., 2017,53, 2543-2546

Permissions

Request permissions

An open route to asymmetric substituted Al–Al bonds using Al(I)- and Al(III)-precursors

B. Li, S. Kundu, H. Zhu, H. Keil, R. Herbst-Irmer, D. Stalke, G. Frenking, D. M. Andrada and H. W. Roesky, Chem. Commun., 2017, 53, 2543 DOI: 10.1039/C7CC00325K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

An open route to asymmetric substituted Al–Al bonds using Al(i)- and Al(iii)-precursors†

Abstract

Supplementary files

Article information

Download Citation

Permissions

An open route to asymmetric substituted Al–Al bonds using Al(I)- and Al(III)-precursors

Social activity

Search articles by author

Spotlight

Advertisements