Issue 22, 2017

Robust high-connected rare-earth MOFs as efficient heterogeneous catalysts for CO2 conversion

Abstract

Two series of chemically and thermally stable rare-earth MOFs were constructed using trinuclear [M33-OH)(COO)6] SBUs and linear dicarboxylate linkers, which feature three-dimensional 12-connected frameworks with an hcp topology. These materials contain a large density of Lewis acidic sites, leading to high catalytic activity towards the cycloaddition of CO2 and epoxides under mild conditions.

Graphical abstract: Robust high-connected rare-earth MOFs as efficient heterogeneous catalysts for CO2 conversion

Supplementary files

Article information

Article type
Communication
Submitted
15 Jan 2017
Accepted
23 Feb 2017
First published
23 Feb 2017

Chem. Commun., 2017,53, 3224-3227

Robust high-connected rare-earth MOFs as efficient heterogeneous catalysts for CO2 conversion

N. Wei, R. Zuo, Y. Zhang, Z. Han and X. Gu, Chem. Commun., 2017, 53, 3224 DOI: 10.1039/C7CC00363C

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