Issue 18, 2017
From the journal:

Chemical Communications

Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters†

Graeme Turnbull, ORCID logo a   J. A. Gareth Williams ORCID logo *b  and  Valery N. Kozhevnikov ORCID logo *a  

* Corresponding authors

a Department of Applied Sciences, Northumbria University, Newcastle upon Tyne
E-mail: valery.kozhevnikov@northumbria.ac.uk

b Department of Chemistry, Durham University, South Road, Durham, UK
E-mail: j.a.g.williams@durham.ac.uk

Abstract

The synthesis and photophysical properties of an unprecedented tetranuclear complex are described, in which a fac-tris-cyclometallated Ir(III) centre is rigidly connected to three cyclometallated Pt(II) centres. The complex absorbs strongly up to ∼600 nm and emits red light with unusually high efficiency.

Graphical abstract: Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters

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Article information

DOI
https://doi.org/10.1039/C7CC00656J
Article type
Communication
Submitted
23 Jan 2017
Accepted
07 Feb 2017
First published
16 Feb 2017
This article is Open Access
Creative Commons BY license

Chem. Commun., 2017,53, 2729-2732

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Rigidly linking cyclometallated Ir(III) and Pt(II) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters

G. Turnbull, J. A. G. Williams and V. N. Kozhevnikov, Chem. Commun., 2017, 53, 2729 DOI: 10.1039/C7CC00656J

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