Issue 32, 2017

Towards a fragment-based approach in gelator design: halogen effects leading to thixotropic, mouldable and self-healing systems in aryl-triazolyl amino acid-based gelators!

Abstract

A simple replacement of a H atom by Br transformed non-gelating aryl triazolyl amino acid benzyl ester into a versatile gelator, which formed shape-persistent, self-healing and mouldable gels. The ‘bromo-aryl benzyl ester’ fragment was then transplanted into another framework, which resulted in similar solvent preference and gelation efficiency.

Graphical abstract: Towards a fragment-based approach in gelator design: halogen effects leading to thixotropic, mouldable and self-healing systems in aryl-triazolyl amino acid-based gelators!

Supplementary files

Article information

Article type
Communication
Submitted
07 Feb 2017
Accepted
23 Mar 2017
First published
28 Mar 2017

Chem. Commun., 2017,53, 4485-4488

Towards a fragment-based approach in gelator design: halogen effects leading to thixotropic, mouldable and self-healing systems in aryl-triazolyl amino acid-based gelators!

B. K. Srivastava and M. K. Manheri, Chem. Commun., 2017, 53, 4485 DOI: 10.1039/C7CC00980A

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