Issue 39, 2017
From the journal:

Chemical Communications

A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation†

Pavel E. Kazin, ORCID logo *a   Mikhail A. Zykin,b   Lev A. Trusov,b   Artem A. Eliseev,b   Oxana V. Magdysyuk,c   Robert E. Dinnebier, ORCID logo d   Reinhard K. Kremer,d   Claudia Felsere  and  Martin Jansende  

* Corresponding authors

a Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia
E-mail: kazin@inorg.chem.msu.ru
Tel: + 7 495 9393440

b Department of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russia

c Diamond Light Source Ltd, Harwell Science and Innovation Campus, OX11 0DE Didcot, UK

d Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany

e Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, 01187 Dresden, Germany

Abstract

An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier Ueff of up to 387 cm−1, which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).

Graphical abstract: A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

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Article information

DOI
https://doi.org/10.1039/C7CC02453C
Article type
Communication
Submitted
30 Mar 2017
Accepted
20 Apr 2017
First published
20 Apr 2017
This article is Open Access
Creative Commons BY license

Chem. Commun., 2017,53, 5416-5419

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A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

P. E. Kazin, M. A. Zykin, L. A. Trusov, A. A. Eliseev, O. V. Magdysyuk, R. E. Dinnebier, R. K. Kremer, C. Felser and M. Jansen, Chem. Commun., 2017, 53, 5416 DOI: 10.1039/C7CC02453C

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