Issue 61, 2017

Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex

Abstract

A clamshell-type terbium(III)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb–Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.

Graphical abstract: Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2017
Accepted
10 Jul 2017
First published
10 Jul 2017

Chem. Commun., 2017,53, 8561-8564

Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocynaninato quadruple-decker complex

Y. Horii, K. Katoh, B. K. Breedlove and M. Yamashita, Chem. Commun., 2017, 53, 8561 DOI: 10.1039/C7CC03553E

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