Issue 67, 2017

Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Abstract

M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn–Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g−1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.

Graphical abstract: Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
29 May 2017
Accepted
31 Jul 2017
First published
08 Aug 2017

Chem. Commun., 2017,53, 9376-9379

Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Y. Liao, L. Zhang, M. H. Weston, W. Morris, J. T. Hupp and O. K. Farha, Chem. Commun., 2017, 53, 9376 DOI: 10.1039/C7CC04160H

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