Issue 63, 2017

Kinetic assembly of coordination networks

Abstract

Kinetic assembly is an important method for obtaining desired materials in chemical synthesis and materials science. We highlight the kinetic assembly of porous coordination networks, which promote the production of interactive pore sites. The interactive pore sites can activate or stabilize guest molecules. The properties of interactive pores are typified by iodine chemisorption and small sulfur encapsulation. Using interactive pores, we trapped small sulfur allotropes, such as S2, cyclo-S3, bent-S3, and S6, demonstrating the importance of interactive pore sites. Here, we address the important aspects of interactive pore sites created by kinetic assembly of porous coordination networks.

Graphical abstract: Kinetic assembly of coordination networks

Article information

Article type
Feature Article
Submitted
02 Jun 2017
Accepted
30 Jun 2017
First published
30 Jun 2017

Chem. Commun., 2017,53, 8818-8829

Kinetic assembly of coordination networks

H. Ohtsu and M. Kawano, Chem. Commun., 2017, 53, 8818 DOI: 10.1039/C7CC04277A

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