Issue 60, 2017

Microwave induced “egg yolk” structure in Cr/V-MIL-53

Abstract

Using a one pot microwave procedure, mixed-metal “egg yolk” MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. In contrast, the solvothermal method produces homogeneous mixed-metal MOFs. The influence of Cr and V on the flexibility and breathing was studied via T-XRPD and CO2 adsorption measurements.

Graphical abstract: Microwave induced “egg yolk” structure in Cr/V-MIL-53

Supplementary files

Article information

Article type
Communication
Submitted
15 Jun 2017
Accepted
04 Jul 2017
First published
04 Jul 2017

Chem. Commun., 2017,53, 8478-8481

Microwave induced “egg yolk” structure in Cr/V-MIL-53

H. Depauw, I. Nevjestić, J. De Winne, G. Wang, K. Haustraete, K. Leus, A. Verberckmoes, C. Detavernier, F. Callens, E. De Canck, H. Vrielinck and P. Van Der Voort, Chem. Commun., 2017, 53, 8478 DOI: 10.1039/C7CC04651K

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